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Registro Completo
Biblioteca(s): |
Embrapa Pecuária Sudeste. |
Data corrente: |
21/11/2018 |
Data da última atualização: |
03/01/2019 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
OLIVEIRA, A. F.; GONZALEZ, M. H.; NOGUEIRA, A. R. de A. |
Afiliação: |
Aline F. Oliveira, UFSCAR; Mario Henrique Gonzalez, UNESP; ANA RITA DE ARAUJO NOGUEIRA, CPPSE. |
Título: |
Use of multiple lines for improving accuracy, minimizing systematic errors from spectral interferences, and reducing matrix effects in MIP OES measurements. |
Ano de publicação: |
2018 |
Fonte/Imprenta: |
Microchemical Journal, v. 143, 2018, p. 326-330. |
DOI: |
10.1016/j.microc.2018.08.032 |
Idioma: |
Inglês |
Conteúdo: |
Bismuth-based medicines, which are generally available without prescription, are used for a variety of purposes including stomach relief, diarrhea, and cold sores. The determination of Bi in these types of medicines using MIP OES is considered easy, due to the relatively high concentrations of this element. However, high dilution factors can lead to systematic errors and thus low precision. Furthermore, the drugs, excipients, and other active pharmaceutical ingredients (APIs) present in these products can cause spectral and matrix interferences. The present study evaluates the use of multiple spectral lines as a strategy to avoid analytical difficulties. For comparative purposes, hydride generation and standard additions techniques were also evaluated. The results demonstrated the feasibility of using the sum of the intensities of multiple lines to improve accuracy, minimizing systematic errors from spectral interferences and matrix effects, employing simple calculations in a data spreadsheet. The accuracies, calculated based on labeled values, varied from 89.2 to 98.8% and from 72.2 to 124% for direct analysis without and with standard additions, respectively, from 73.2 to 114% for hydride generation, and from 89.8 to 101% for the multiple lines sum method. |
Palavras-Chave: |
Geração de hidreto; MIP OES. |
Thesagro: |
Análise Química. |
Thesaurus NAL: |
Bismuth. |
Categoria do assunto: |
W Química e Física |
Marc: |
LEADER 01970naa a2200205 a 4500 001 2099737 005 2019-01-03 008 2018 bl uuuu u00u1 u #d 024 7 $a10.1016/j.microc.2018.08.032$2DOI 100 1 $aOLIVEIRA, A. F. 245 $aUse of multiple lines for improving accuracy, minimizing systematic errors from spectral interferences, and reducing matrix effects in MIP OES measurements.$h[electronic resource] 260 $c2018 520 $aBismuth-based medicines, which are generally available without prescription, are used for a variety of purposes including stomach relief, diarrhea, and cold sores. The determination of Bi in these types of medicines using MIP OES is considered easy, due to the relatively high concentrations of this element. However, high dilution factors can lead to systematic errors and thus low precision. Furthermore, the drugs, excipients, and other active pharmaceutical ingredients (APIs) present in these products can cause spectral and matrix interferences. The present study evaluates the use of multiple spectral lines as a strategy to avoid analytical difficulties. For comparative purposes, hydride generation and standard additions techniques were also evaluated. The results demonstrated the feasibility of using the sum of the intensities of multiple lines to improve accuracy, minimizing systematic errors from spectral interferences and matrix effects, employing simple calculations in a data spreadsheet. The accuracies, calculated based on labeled values, varied from 89.2 to 98.8% and from 72.2 to 124% for direct analysis without and with standard additions, respectively, from 73.2 to 114% for hydride generation, and from 89.8 to 101% for the multiple lines sum method. 650 $aBismuth 650 $aAnálise Química 653 $aGeração de hidreto 653 $aMIP OES 700 1 $aGONZALEZ, M. H. 700 1 $aNOGUEIRA, A. R. de A. 773 $tMicrochemical Journal$gv. 143, 2018, p. 326-330.
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